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101.
In this paper, we define a new constrained multi-component KP(cMKP) hierarchy which contains the constrained KP(cKP) hierarchy as a special case. We derive the recursion operator of the constrained multi-component KP hierarchy. As a special example, we also give the recursion operator of the constrained two-component KP hierarchy. 相似文献
102.
In this paper, we will use the Schwarz lemma at the boundary to character the distortion theorems of determinant at the extreme points and distortion theorems of matrix on the complex tangent space at the extreme points for normalized locally biholomorphic quasi-convex mappings in the unit ball B n respectively. 相似文献
103.
基于格林函数理论,主要利用Lerray-Schauder抉择定理和上下解方法针对半正定条件下,奇异超线性二阶周期边值问题正解的存在性进行推理证明,获取了奇异超线性二阶周期边值问题的一个正解. 相似文献
104.
复杂网络广泛存在于日常生活,首先,给出几类标准的网络模型;然后,利用稳定性控制方法设计并实现了具有时滞与非时滞耦合的复杂网络模型快速控制;最后,通过构造优化Lyapunov函数,讨论其模型的射影同步问题,得到了系统全局稳定的条件和有效的控制器,以实例数值验证其方法的可行性。 相似文献
105.
利用ALD制备了TiO2限域的Pd催化剂, 研究了限域空间内Pd纳米颗粒与TiO2的界面作用对1,4-丁炔二醇(BYD)加氢性能的影响. 相比于管外负载型催化剂, 限域催化剂在催化1,4-丁炔二醇选择性加氢反应中体现出非常高的催化活性和1,4-丁烯二醇的选择性. HR-TEM、 EDX-Mapping、 XRD、 XPS和H2-TPR表征说明, 限域体系中Pd-TiO2的界面相互作用强于传统TiO2表面负载型Pd催化剂, 这种强界面作用不仅能够提高BYD的加氢活性, 也可抑制半加氢产物1,4-丁烯二醇的异构化和深度加氢, 提高1,4-丁烯二醇的选择性, 而且限域结构也可阻止管内壁Pd纳米颗粒的脱落, 提高催化剂的稳定性. 相似文献
106.
1902年,瑞士化学家维尔纳对氯化铵结构的解释为氢键概念的形成奠定了基础。1920年,美国化学家拉提麦尔和罗德布什首先认识了水中的氢键:2个八隅体所持的氢核构成的“弱键(weak bond)”。1928年,美国化学家鲍林在解释[FHF]-的结构时首次使用“氢键(hydrogen bond)”一词,但并未对氢键的概念进行明确定义。1939年,鲍林在《化学键的本质》中明确提出了氢键的概念,并解释了氢键的性质,自此,氢键的概念正式形成。近年来,科学家经过深入研究发现了氢键的新类型:π型氢键、双氢键、金属氢键和单电子氢键。随着科学思想和科学技术的发展,关于氢键的认识也会越来越深入。 相似文献
107.
Xiaoyu Liu Haolin Lu Prof. Shengli Zhu Prof. Zhenduo Cui Prof. Zhaoyang Li Prof. Shuilin Wu Prof. Wence Xu Prof. Yanqin Liang Prof. Guankui Long Prof. Hui Jiang 《Angewandte Chemie (International ed. in English)》2023,62(13):e202300800
It is challenging to design one non-noble material with balanced bifunctional performance for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) for commercial sustainability at a low cost since the different electrocatalytic mechanisms are not easily matchable for each other. Herein, a self-standing hybrid system Ni18Fe12Al70, consisting of Ni2Al3 and Ni3Fe phases, was constructed by laser-assisted aluminum (Al) incorporation towards full water splitting. It was found that the incorporation of Al could effectively tune the morphologies, compositions and phases. The results indicate that Ni18Fe12Al70 delivers an extremely low overpotential to trigger both HER (η100=188 mV) and OER (η100=345 mV) processes and maintains a stable overpotential for 100 h, comparable to state-of-the-art electrocatalysts. The synergistic effect of Ni2Al3 and Ni3Fe alloys on the HER process is confirmed based on theoretical calculation. 相似文献
108.
Wei Gao Yaxin Qin Yaping Zang Jiaming Zhu Wei Chen Shengqiang Tong Yuqun Zeng Chu Chu 《Journal of separation science》2023,46(17):2300164
Accurate quantitative analysis of trace analytes in a complicated matrix is a challenge in modern analytical chemistry. An appropriate analytical method is considered to be one of the most common gaps during the whole process. In this study, a green and efficient strategy based on miniaturized matrix solid-phase dispersion and solid-phase extraction combined with capillary electrophoresis was first proposed for extracting, purifying and determining target analytes from complicated matrix, using Wubi Shanyao Pill as an example. In detail, 60 mg of samples were dispersed on MCM-48 to obtain high yields of analytes, then the extract was purified with a solid-phase extraction cartridge. Finally, four analytes in the purified sample solution were determined by capillary electrophoresis. The parameters affecting the extraction efficiency of matrix solid-phase dispersion, purification efficiency of solid-phase extraction and separation effect of capillary electrophoresis were investigated. Under the optimized conditions, all analytes demonstrated satisfactory linearity (R2>0.9983). What's more, the superior green potential of the developed method for the determination of complex samples was confirmed by the Analytical GREEnness Metric Approach. The established method was successfully applied in the accurate determination of target analytes in Wubi Shanyao Pill and thus provided reliable, sensitive, and efficient strategy support for its quality control. 相似文献
109.
《Arabian Journal of Chemistry》2023,16(4):104589
PurposeThe purpose of the current framework is to scrutinize the two-dimensional flow and heat transfer of Casson nanofluid over cylinder/plate along with impacts of thermophoresis and Brownian motion effects. Also, the effects of exponential thermal sink/source, bioconvection, and motile microorganisms are taken.Methodology/ApproachThe resulting non-linear equations (PDEs) are reformed into nonlinear ODEs by using appropriate similarity variables. The resultant non-linear (ODEs) were numerically evaluated by the use of the Bvp4c package in the mathematical solver MATLAB.FindingsThe numerical and graphical illustration regarding outcomes represents the performance of flow-involved physical parameters on velocity, temperature, concentration, and microorganism profiles. Additionally, the skin friction coefficient, local Nusselt number, local Sherwood number, and local microorganism density number are computed numerically for the current presented system. We noted that the velocity profile diminishes for the rising estimations of magnetic and mixed convection parameters. The Prandtl number corresponds with the declining performance of the temperature profile observed. The enhancement in the values of the Solutal Biot number and Brownian motion parameter increased in the concentration profile.OriginalityIn specific, this framework focuses on the rising heat transfer of Casson nanofluid with bioconvection by using a shooting mathematical model. The novel approach of the presented study is the use of motile microorganisms with exponential thermal sink/source in a Casson nano-fluid through a cylinder/plate. A presented study performed first time in the author’s opinion. Understanding the flow characteristics and behaviors of these nanofluids is crucial for the scientific community in the developing subject of nanofluids. 相似文献
110.
Fabien Pascale Klaus Doll Francesco Silvio Gentile Roberto Dovesi 《Journal of computational chemistry》2023,44(2):65-75
The ferromagnetic and antiferromagnetic wave functions of the KMnF3 perovskite have been evaluated quantum-mechanically by using an all electron approach and, for comparison, pseudopotentials on the transition metal and the fluorine ions. It is shown that the different number of α and β electrons in the d shell of Mn perturbs the inner shells, with shifts between the α and β eigenvalues that can be as large as 6 eV for the 3s level, and is far from negligible also for the 2s and 2p states. The valence electrons of F are polarized by the majority spin electrons of Mn, and in turn, spin polarize their 1s electrons. When a pseudopotential is used, such a spin polarization of the core functions of Mn and F can obviously not take place. The importance of such a spin polarization can be appreciated by comparing (i) the spin density at the Mn and F nuclear position, and then the Fermi contact constant, a crucial quantity for the hyperfine coupling, and (ii) the ferromagnetic–antiferromagnetic energy difference, when obtained with an all electron or a pseudopotential scheme, and exploring how the latter varies with pressure. This difference is as large as 50% of the all electron datum, and is mainly due to the rigid treatment of the F ion core. The effect of five different functionals on the core spin polarization is documented. 相似文献